Driver fatigue is thought to be responsible for as many as a fifth of road crashes across the EU, although there are certain times of the day when more accidents happen.
据认为,驾驶员疲劳是欧盟境内多达五分之一道路交通事故的原因之一,尽管一天中的某些时段发生的事故更多。
该从句紧跟先行词 "times of the day",限定具体是哪一些时段,即“事故发生得更多的时段”。关系副词 "when" 在从句中表示时间状语,相当于 "during which";没有逗号,属于限制性定语从句。